Enhanced performance of perovskite solar cells by modulating the Lewis acid-base reaction.

نویسندگان

  • Xiaobing Cao
  • Changli Li
  • Yahui Li
  • Fei Fang
  • Xian Cui
  • Youwei Yao
  • Jinquan Wei
چکیده

The Lewis acid-base reaction between PbI2 and solvent molecules is popular in fabricating PbI2 films by a two-step method for making perovskite solar cells. Here, we control the microstructure of PbI2 films through modulating the Lewis acid-base reaction by adding a small amount of N-methyl pyrrolidone into PbI2/DMF solution. PbI2 films with excellent crystallinity and full coverage are fabricated by spin-coating the mixed solution on the substrate, which leads to high quality perovskite layers with low recombination rate and high efficiency for carrier transfer. As a result, the power conversion efficiency of the best perovskite solar cells increases from 13.3% to 17.5%.

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عنوان ژورنال:
  • Nanoscale

دوره 8 47  شماره 

صفحات  -

تاریخ انتشار 2016